"and when the sun was hot (i.e., strong), it melted: in the fourth hour (of the day). You say, in the fourth hour; but perhaps (the intent is) in the sixth hour? (This is not so, for) "when the sun was hot" implies when the sun (i.e., an unshaded spot) was hot and the shade was cool — the fourth hour (and not the sixth.)
Why the Fourth Hour and Not the Sixth
Mekhilta Tractate Vayassa 5:5